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Determination of Gd concentration profile in UO2-Gd2O3 fuel pellets

机译:UO2-Gd2O3燃料芯块中Gd浓度分布的测定

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摘要

A transversal mapping of the Gd concentration was measured in UO2-Gd2O3nuclear fuel pellets by electron paramagnetic resonance spectroscopy (EPR). Thequantification was made from the comparison with a Gd2O3 reference sample. Thenominal concentration in the pellets is UO2: 7.5 % Gd2O3. A concentrationgradient was found, which indicates that the Gd2O3 amount diminishes towardsthe edges of the pellets. The concentration varies from (9.3 +/- 0.5)% in thecenter to (5.8 +/- 0.3)% in one of the edges. The method was found to beparticularly suitable for the precise mapping of the distribution of Gd3+ ionsin the UO2 matrix.
机译:通过电子顺磁共振波谱(EPR)测量了UO2-Gd2O3核燃料芯块中Gd浓度的横向图。通过与Gd2O3参考样品的比较进行量化。颗粒中的标称浓度为UO2:7.5%Gd2O3。发现浓度梯度,其表明Gd 2 O 3的量朝向丸粒的边缘减少。浓度从中心的(9.3 +/- 0.5)%到边缘之一的(5.8 +/- 0.3)%不等。发现该方法特别适用于精确映射UO2基质中Gd3 +离子的分布。

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